# Materials Library
import numpy as np

import meep as mp

# default unit length is 1 μm
um_scale = 1.0

# conversion factor for eV to 1/μm [=1/hc]
eV_um_scale = um_scale / 1.23984193

# ------------------------------------------------------------------
# crystalline silicon (c-Si) from A. Deinega et al., J. Optical Society of America A, Vol. 28, No. 5, pp. 770-77 (2011)
# based on experimental data for intrinsic silicon at T=300K from M.A. Green and M. Keevers, Progress in Photovoltaics, Vol. 3, pp. 189-92 (1995)
# wavelength range: 0.4 - 1.0 μm

cSi_range = mp.FreqRange(min=um_scale, max=um_scale / 0.4)

cSi_frq1 = 3.64 / um_scale
cSi_gam1 = 0
cSi_sig1 = 8
cSi_frq2 = 2.76 / um_scale
cSi_gam2 = 2 * 0.063 / um_scale
cSi_sig2 = 2.85
cSi_frq3 = 1.73 / um_scale
cSi_gam3 = 2 * 2.5 / um_scale
cSi_sig3 = -0.107

cSi_susc = [
    mp.LorentzianSusceptibility(frequency=cSi_frq1, gamma=cSi_gam1, sigma=cSi_sig1),
    mp.LorentzianSusceptibility(frequency=cSi_frq2, gamma=cSi_gam2, sigma=cSi_sig2),
    mp.LorentzianSusceptibility(frequency=cSi_frq3, gamma=cSi_gam3, sigma=cSi_sig3),
]

cSi = mp.Medium(epsilon=1.0, E_susceptibilities=cSi_susc, valid_freq_range=cSi_range)

# ------------------------------------------------------------------
# amorphous silicon (a-Si) from Horiba Technical Note 08: Lorentz Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Lorentz_Dispersion_Model.pdf
# wavelength range: 0.21 - 0.83 μm

aSi_range = mp.FreqRange(min=um_scale / 0.83, max=um_scale / 0.21)

aSi_frq1 = 1 / (0.315481407124682 * um_scale)
aSi_gam1 = 1 / (0.645751005208333 * um_scale)
aSi_sig1 = 14.571

aSi_susc = [
    mp.LorentzianSusceptibility(frequency=aSi_frq1, gamma=aSi_gam1, sigma=aSi_sig1)
]

aSi = mp.Medium(epsilon=3.109, E_susceptibilities=aSi_susc, valid_freq_range=aSi_range)

# ------------------------------------------------------------------
# hydrogenated amorphous silicon (a-Si:H) from Horiba Technical Note 08: Lorentz Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Lorentz_Dispersion_Model.pdf
# wavelength range: 0.21 - 0.83 μm

aSi_H_range = mp.FreqRange(min=um_scale / 0.83, max=um_scale / 0.21)

aSi_H_frq1 = 1 / (0.334189199460916 * um_scale)
aSi_H_gam1 = 1 / (0.579365387850467 * um_scale)
aSi_H_sig1 = 12.31

aSi_H_susc = [
    mp.LorentzianSusceptibility(
        frequency=aSi_H_frq1, gamma=aSi_H_gam1, sigma=aSi_H_sig1
    )
]

aSi_H = mp.Medium(
    epsilon=3.22, E_susceptibilities=aSi_H_susc, valid_freq_range=aSi_H_range
)

# ------------------------------------------------------------------
# indium tin oxide (ITO) from Horiba Technical Note 08: Lorentz Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Lorentz_Dispersion_Model.pdf
# wavelength range: 0.21 - 0.83 μm

ITO_range = mp.FreqRange(min=um_scale / 0.83, max=um_scale / 0.21)

ITO_frq1 = 1 / (0.182329695588235 * um_scale)
ITO_gam1 = 1 / (1.94637665620094 * um_scale)
ITO_sig1 = 2.5

ITO_susc = [
    mp.LorentzianSusceptibility(frequency=ITO_frq1, gamma=ITO_gam1, sigma=ITO_sig1)
]

ITO = mp.Medium(epsilon=1.0, E_susceptibilities=ITO_susc, valid_freq_range=ITO_range)

# ------------------------------------------------------------------
# alumina (Al2O3) from Horiba Technical Note 08: Lorentz Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Lorentz_Dispersion_Model.pdf
# wavelength range: 0.21 - 2.07 μm

Al2O3_range = mp.FreqRange(min=um_scale / 2.07, max=um_scale / 0.21)

Al2O3_frq1 = 1 / (0.101476668030774 * um_scale)
Al2O3_gam1 = 0
Al2O3_sig1 = 1.52

Al2O3_susc = [
    mp.LorentzianSusceptibility(
        frequency=Al2O3_frq1, gamma=Al2O3_gam1, sigma=Al2O3_sig1
    )
]

Al2O3 = mp.Medium(
    epsilon=1.0, E_susceptibilities=Al2O3_susc, valid_freq_range=Al2O3_range
)

# ------------------------------------------------------------------
# aluminum nitride (AlN) from Horiba Technical Note 08: Lorentz Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Lorentz_Dispersion_Model.pdf
# wavelength range: 0.26 - 1.65 μm

AlN_range = mp.FreqRange(min=um_scale / 1.65, max=um_scale / 0.26)

AlN_frq1 = 1 / (0.139058089950651 * um_scale)
AlN_gam1 = 0
AlN_sig1 = 3.306

AlN_susc = [
    mp.LorentzianSusceptibility(frequency=AlN_frq1, gamma=AlN_gam1, sigma=AlN_sig1)
]

AlN = mp.Medium(epsilon=1.0, E_susceptibilities=AlN_susc, valid_freq_range=AlN_range)

# ------------------------------------------------------------------
# aluminum arsenide (AlAs) from R.E. Fern and A. Onton, J. Applied Physics, Vol. 42, pp. 3499-500 (1971)
# ref: https://refractiveindex.info/?shelf=main&book=AlAs&page=Fern
# wavelength range: 0.56 - 2.2 μm

AlAs_range = mp.FreqRange(min=um_scale / 2.2, max=um_scale / 0.56)

AlAs_frq1 = 1 / (0.2822 * um_scale)
AlAs_gam1 = 0
AlAs_sig1 = 6.0840
AlAs_frq2 = 1 / (27.62 * um_scale)
AlAs_gam2 = 0
AlAs_sig2 = 1.900

AlAs_susc = [
    mp.LorentzianSusceptibility(frequency=AlAs_frq1, gamma=AlAs_gam1, sigma=AlAs_sig1),
    mp.LorentzianSusceptibility(frequency=AlAs_frq2, gamma=AlAs_gam2, sigma=AlAs_sig2),
]

AlAs = mp.Medium(
    epsilon=2.0792, E_susceptibilities=AlAs_susc, valid_freq_range=AlAs_range
)

# ------------------------------------------------------------------
# borosilicate glass (BK7) from SCHOTT Zemax catalog 2017-01-20b
# ref: https://refractiveindex.info/?shelf=glass&book=BK7&page=SCHOTT
# wavelength range: 0.3 - 2.5 μm

BK7_range = mp.FreqRange(min=um_scale / 2.5, max=um_scale / 0.3)

BK7_frq1 = 1 / (0.07746417668832478 * um_scale)
BK7_gam1 = 0
BK7_sig1 = 1.03961212
BK7_frq2 = 1 / (0.14148467902921502 * um_scale)
BK7_gam2 = 0
BK7_sig2 = 0.231792344
BK7_frq3 = 1 / (10.176475470417055 * um_scale)
BK7_gam3 = 0
BK7_sig3 = 1.01046945

BK7_susc = [
    mp.LorentzianSusceptibility(frequency=BK7_frq1, gamma=BK7_gam1, sigma=BK7_sig1),
    mp.LorentzianSusceptibility(frequency=BK7_frq2, gamma=BK7_gam2, sigma=BK7_sig2),
    mp.LorentzianSusceptibility(frequency=BK7_frq3, gamma=BK7_gam3, sigma=BK7_sig3),
]

BK7 = mp.Medium(epsilon=1.0, E_susceptibilities=BK7_susc, valid_freq_range=BK7_range)

# ------------------------------------------------------------------
# fused quartz (silica) from I.H. Malitson, J. Optical Society of America, Vol. 55, pp. 1205-9 (1965)
# ref: https://refractiveindex.info/?shelf=glass&book=fused_silica&page=Malitson
# wavelength range: 0.21 - 6.7 μm

fused_quartz_range = mp.FreqRange(min=um_scale / 6.7, max=um_scale / 0.21)

fused_quartz_frq1 = 1 / (0.0684043 * um_scale)
fused_quartz_gam1 = 0
fused_quartz_sig1 = 0.696166300
fused_quartz_frq2 = 1 / (0.1162414 * um_scale)
fused_quartz_gam2 = 0
fused_quartz_sig2 = 0.407942600
fused_quartz_frq3 = 1 / (9.896161 * um_scale)
fused_quartz_gam3 = 0
fused_quartz_sig3 = 0.897479400

fused_quartz_susc = [
    mp.LorentzianSusceptibility(
        frequency=fused_quartz_frq1, gamma=fused_quartz_gam1, sigma=fused_quartz_sig1
    ),
    mp.LorentzianSusceptibility(
        frequency=fused_quartz_frq2, gamma=fused_quartz_gam2, sigma=fused_quartz_sig2
    ),
    mp.LorentzianSusceptibility(
        frequency=fused_quartz_frq3, gamma=fused_quartz_gam3, sigma=fused_quartz_sig3
    ),
]

fused_quartz = mp.Medium(
    epsilon=1.0,
    E_susceptibilities=fused_quartz_susc,
    valid_freq_range=fused_quartz_range,
)

# ------------------------------------------------------------------
# gallium arsenide (GaAs) from T. Skauli et al., J. Applied Physics, Vol. 94, pp. 6447-55 (2003)
# ref: https://refractiveindex.info/?shelf=main&book=GaAs&page=Skauli
# wavelength range: 0.97 - 17 μm

GaAs_range = mp.FreqRange(min=um_scale / 17, max=um_scale / 0.97)

GaAs_frq1 = 1 / (0.4431307 * um_scale)
GaAs_gam1 = 0
GaAs_sig1 = 5.466742
GaAs_frq2 = 1 / (0.8746453 * um_scale)
GaAs_gam2 = 0
GaAs_sig2 = 0.02429960
GaAs_frq3 = 1 / (36.9166 * um_scale)
GaAs_gam3 = 0
GaAs_sig3 = 1.957522

GaAs_susc = [
    mp.LorentzianSusceptibility(frequency=GaAs_frq1, gamma=GaAs_gam1, sigma=GaAs_sig1),
    mp.LorentzianSusceptibility(frequency=GaAs_frq2, gamma=GaAs_gam2, sigma=GaAs_sig2),
    mp.LorentzianSusceptibility(frequency=GaAs_frq3, gamma=GaAs_gam3, sigma=GaAs_sig3),
]

GaAs = mp.Medium(
    epsilon=5.372514, E_susceptibilities=GaAs_susc, valid_freq_range=GaAs_range
)

# ------------------------------------------------------------------
# silicon nitride (Si3N4) from H. R. Philipp, J. Electrochemical Society 120, 295-300 (1973)
# ref: https://refractiveindex.info/?shelf=main&book=Si3N4&page=Philipp
# wavelength range: 0.207 - 1.24 μm

Si3N4_VISNIR_range = mp.FreqRange(min=um_scale / 1.24, max=um_scale / 0.207)

Si3N4_VISNIR_frq1 = 1 / (0.13967 * um_scale)
Si3N4_VISNIR_gam1 = 0
Si3N4_VISNIR_sig1 = 2.8939

Si3N4_VISNIR_susc = [
    mp.LorentzianSusceptibility(
        frequency=Si3N4_VISNIR_frq1, gamma=Si3N4_VISNIR_gam1, sigma=Si3N4_VISNIR_sig1
    )
]

Si3N4_VISNIR = mp.Medium(
    epsilon=1.0,
    E_susceptibilities=Si3N4_VISNIR_susc,
    valid_freq_range=Si3N4_VISNIR_range,
)

# ------------------------------------------------------------------
# silicon nitride (Si3N4) from K. Luke, et. al., Optics Letters, Vol. 40, pp. 4823-26 (2015)
# ref: https://refractiveindex.info/?shelf=main&book=Si3N4&page=Luke
# wavelength range: 0.310 - 5.504 μm

Si3N4_NIR_range = mp.FreqRange(min=um_scale / 5.504, max=um_scale / 0.310)

Si3N4_NIR_frq1 = 1 / (0.1353406 * um_scale)
Si3N4_NIR_gam1 = 0
Si3N4_NIR_sig1 = 3.0249
Si3N4_NIR_frq2 = 1 / (1239.842 * um_scale)
Si3N4_NIR_gam2 = 0
Si3N4_NIR_sig2 = 40314

Si3N4_NIR_susc = [
    mp.LorentzianSusceptibility(
        frequency=Si3N4_NIR_frq1, gamma=Si3N4_NIR_gam1, sigma=Si3N4_NIR_sig1
    ),
    mp.LorentzianSusceptibility(
        frequency=Si3N4_NIR_frq2, gamma=Si3N4_NIR_gam2, sigma=Si3N4_NIR_sig2
    ),
]

Si3N4_NIR = mp.Medium(
    epsilon=1.0, E_susceptibilities=Si3N4_NIR_susc, valid_freq_range=Si3N4_NIR_range
)

# ------------------------------------------------------------------
# elemental metals from A.D. Rakic et al., Applied Optics, Vol. 37, No. 22, pp. 5271-83 (1998)
# wavelength range: 0.2 - 12.4 μm

metal_range = mp.FreqRange(min=um_scale / 12.398, max=um_scale / 0.24797)

# silver (Ag)

Ag_plasma_frq = 9.01 * eV_um_scale
Ag_f0 = 0.845
Ag_frq0 = 1e-10
Ag_gam0 = 0.048 * eV_um_scale
Ag_sig0 = Ag_f0 * Ag_plasma_frq**2 / Ag_frq0**2
Ag_f1 = 0.065
Ag_frq1 = 0.816 * eV_um_scale  # 1.519 μm
Ag_gam1 = 3.886 * eV_um_scale
Ag_sig1 = Ag_f1 * Ag_plasma_frq**2 / Ag_frq1**2
Ag_f2 = 0.124
Ag_frq2 = 4.481 * eV_um_scale  # 0.273 μm
Ag_gam2 = 0.452 * eV_um_scale
Ag_sig2 = Ag_f2 * Ag_plasma_frq**2 / Ag_frq2**2
Ag_f3 = 0.011
Ag_frq3 = 8.185 * eV_um_scale  # 0.152 μm
Ag_gam3 = 0.065 * eV_um_scale
Ag_sig3 = Ag_f3 * Ag_plasma_frq**2 / Ag_frq3**2
Ag_f4 = 0.840
Ag_frq4 = 9.083 * eV_um_scale  # 0.137 μm
Ag_gam4 = 0.916 * eV_um_scale
Ag_sig4 = Ag_f4 * Ag_plasma_frq**2 / Ag_frq4**2
Ag_f5 = 5.646
Ag_frq5 = 20.29 * eV_um_scale  # 0.061 μm
Ag_gam5 = 2.419 * eV_um_scale
Ag_sig5 = Ag_f5 * Ag_plasma_frq**2 / Ag_frq5**2

Ag_susc = [
    mp.DrudeSusceptibility(frequency=Ag_frq0, gamma=Ag_gam0, sigma=Ag_sig0),
    mp.LorentzianSusceptibility(frequency=Ag_frq1, gamma=Ag_gam1, sigma=Ag_sig1),
    mp.LorentzianSusceptibility(frequency=Ag_frq2, gamma=Ag_gam2, sigma=Ag_sig2),
    mp.LorentzianSusceptibility(frequency=Ag_frq3, gamma=Ag_gam3, sigma=Ag_sig3),
    mp.LorentzianSusceptibility(frequency=Ag_frq4, gamma=Ag_gam4, sigma=Ag_sig4),
    mp.LorentzianSusceptibility(frequency=Ag_frq5, gamma=Ag_gam5, sigma=Ag_sig5),
]

Ag = mp.Medium(epsilon=1.0, E_susceptibilities=Ag_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# gold (Au)

metal_range = mp.FreqRange(min=um_scale / 6.1992, max=um_scale / 0.24797)

Au_plasma_frq = 9.03 * eV_um_scale
Au_f0 = 0.760
Au_frq0 = 1e-10
Au_gam0 = 0.053 * eV_um_scale
Au_sig0 = Au_f0 * Au_plasma_frq**2 / Au_frq0**2
Au_f1 = 0.024
Au_frq1 = 0.415 * eV_um_scale  # 2.988 μm
Au_gam1 = 0.241 * eV_um_scale
Au_sig1 = Au_f1 * Au_plasma_frq**2 / Au_frq1**2
Au_f2 = 0.010
Au_frq2 = 0.830 * eV_um_scale  # 1.494 μm
Au_gam2 = 0.345 * eV_um_scale
Au_sig2 = Au_f2 * Au_plasma_frq**2 / Au_frq2**2
Au_f3 = 0.071
Au_frq3 = 2.969 * eV_um_scale  # 0.418 μm
Au_gam3 = 0.870 * eV_um_scale
Au_sig3 = Au_f3 * Au_plasma_frq**2 / Au_frq3**2
Au_f4 = 0.601
Au_frq4 = 4.304 * eV_um_scale  # 0.288 μm
Au_gam4 = 2.494 * eV_um_scale
Au_sig4 = Au_f4 * Au_plasma_frq**2 / Au_frq4**2
Au_f5 = 4.384
Au_frq5 = 13.32 * eV_um_scale  # 0.093 μm
Au_gam5 = 2.214 * eV_um_scale
Au_sig5 = Au_f5 * Au_plasma_frq**2 / Au_frq5**2

Au_susc = [
    mp.DrudeSusceptibility(frequency=Au_frq0, gamma=Au_gam0, sigma=Au_sig0),
    mp.LorentzianSusceptibility(frequency=Au_frq1, gamma=Au_gam1, sigma=Au_sig1),
    mp.LorentzianSusceptibility(frequency=Au_frq2, gamma=Au_gam2, sigma=Au_sig2),
    mp.LorentzianSusceptibility(frequency=Au_frq3, gamma=Au_gam3, sigma=Au_sig3),
    mp.LorentzianSusceptibility(frequency=Au_frq4, gamma=Au_gam4, sigma=Au_sig4),
    mp.LorentzianSusceptibility(frequency=Au_frq5, gamma=Au_gam5, sigma=Au_sig5),
]

Au = mp.Medium(epsilon=1.0, E_susceptibilities=Au_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# copper (Cu)

metal_range = mp.FreqRange(min=um_scale / 12.398, max=um_scale / 0.20664)

Cu_plasma_frq = 10.83 * eV_um_scale
Cu_f0 = 0.575
Cu_frq0 = 1e-10
Cu_gam0 = 0.030 * eV_um_scale
Cu_sig0 = Cu_f0 * Cu_plasma_frq**2 / Cu_frq0**2
Cu_f1 = 0.061
Cu_frq1 = 0.291 * eV_um_scale  # 4.261 μm
Cu_gam1 = 0.378 * eV_um_scale
Cu_sig1 = Cu_f1 * Cu_plasma_frq**2 / Cu_frq1**2
Cu_f2 = 0.104
Cu_frq2 = 2.957 * eV_um_scale  # 0.419 μm
Cu_gam2 = 1.056 * eV_um_scale
Cu_sig2 = Cu_f2 * Cu_plasma_frq**2 / Cu_frq2**2
Cu_f3 = 0.723
Cu_frq3 = 5.300 * eV_um_scale  # 0.234 μm
Cu_gam3 = 3.213 * eV_um_scale
Cu_sig3 = Cu_f3 * Cu_plasma_frq**2 / Cu_frq3**2
Cu_f4 = 0.638
Cu_frq4 = 11.18 * eV_um_scale  # 0.111 μm
Cu_gam4 = 4.305 * eV_um_scale
Cu_sig4 = Cu_f4 * Cu_plasma_frq**2 / Cu_frq4**2

Cu_susc = [
    mp.DrudeSusceptibility(frequency=Cu_frq0, gamma=Cu_gam0, sigma=Cu_sig0),
    mp.LorentzianSusceptibility(frequency=Cu_frq1, gamma=Cu_gam1, sigma=Cu_sig1),
    mp.LorentzianSusceptibility(frequency=Cu_frq2, gamma=Cu_gam2, sigma=Cu_sig2),
    mp.LorentzianSusceptibility(frequency=Cu_frq3, gamma=Cu_gam3, sigma=Cu_sig3),
    mp.LorentzianSusceptibility(frequency=Cu_frq4, gamma=Cu_gam4, sigma=Cu_sig4),
]

Cu = mp.Medium(epsilon=1.0, E_susceptibilities=Cu_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# aluminum (Al)

Al_plasma_frq = 14.98 * eV_um_scale
Al_f0 = 0.523
Al_frq0 = 1e-10
Al_gam0 = 0.047 * eV_um_scale
Al_sig0 = Al_f0 * Al_plasma_frq**2 / Al_frq0**2
Al_f1 = 0.227
Al_frq1 = 0.162 * eV_um_scale  # 7.654 μm
Al_gam1 = 0.333 * eV_um_scale
Al_sig1 = Al_f1 * Al_plasma_frq**2 / Al_frq1**2
Al_f2 = 0.050
Al_frq2 = 1.544 * eV_um_scale  # 0.803 μm
Al_gam2 = 0.312 * eV_um_scale
Al_sig2 = Al_f2 * Al_plasma_frq**2 / Al_frq2**2
Al_f3 = 0.166
Al_frq3 = 1.808 * eV_um_scale  # 0.686 μm
Al_gam3 = 1.351 * eV_um_scale
Al_sig3 = Al_f3 * Al_plasma_frq**2 / Al_frq3**2
Al_f4 = 0.030
Al_frq4 = 3.473 * eV_um_scale  # 0.357 μm
Al_gam4 = 3.382 * eV_um_scale
Al_sig4 = Al_f4 * Al_plasma_frq**2 / Al_frq4**2

Al_susc = [
    mp.DrudeSusceptibility(frequency=Al_frq0, gamma=Al_gam0, sigma=Al_sig0),
    mp.LorentzianSusceptibility(frequency=Al_frq1, gamma=Al_gam1, sigma=Al_sig1),
    mp.LorentzianSusceptibility(frequency=Al_frq2, gamma=Al_gam2, sigma=Al_sig2),
    mp.LorentzianSusceptibility(frequency=Al_frq3, gamma=Al_gam3, sigma=Al_sig3),
    mp.LorentzianSusceptibility(frequency=Al_frq4, gamma=Al_gam4, sigma=Al_sig4),
]

Al = mp.Medium(epsilon=1.0, E_susceptibilities=Al_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# beryllium (Be)

Be_plasma_frq = 18.51 * eV_um_scale
Be_f0 = 0.084
Be_frq0 = 1e-10
Be_gam0 = 0.035 * eV_um_scale
Be_sig0 = Be_f0 * Be_plasma_frq**2 / Be_frq0**2
Be_f1 = 0.031
Be_frq1 = 0.100 * eV_um_scale  # 12.398 μm
Be_gam1 = 1.664 * eV_um_scale
Be_sig1 = Be_f1 * Be_plasma_frq**2 / Be_frq1**2
Be_f2 = 0.140
Be_frq2 = 1.032 * eV_um_scale  # 1.201 μm
Be_gam2 = 3.395 * eV_um_scale
Be_sig2 = Be_f2 * Be_plasma_frq**2 / Be_frq2**2
Be_f3 = 0.530
Be_frq3 = 3.183 * eV_um_scale  # 0.390 μm
Be_gam3 = 4.454 * eV_um_scale
Be_sig3 = Be_f3 * Be_plasma_frq**2 / Be_frq3**2
Be_f4 = 0.130
Be_frq4 = 4.604 * eV_um_scale  # 0.269 μm
Be_gam4 = 1.802 * eV_um_scale
Be_sig4 = Be_f4 * Be_plasma_frq**2 / Be_frq4**2

Be_susc = [
    mp.DrudeSusceptibility(frequency=Be_frq0, gamma=Be_gam0, sigma=Be_sig0),
    mp.LorentzianSusceptibility(frequency=Be_frq1, gamma=Be_gam1, sigma=Be_sig1),
    mp.LorentzianSusceptibility(frequency=Be_frq2, gamma=Be_gam2, sigma=Be_sig2),
    mp.LorentzianSusceptibility(frequency=Be_frq3, gamma=Be_gam3, sigma=Be_sig3),
    mp.LorentzianSusceptibility(frequency=Be_frq4, gamma=Be_gam4, sigma=Be_sig4),
]

Be = mp.Medium(epsilon=1.0, E_susceptibilities=Be_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# chromium (Cr)

Cr_plasma_frq = 10.75 * eV_um_scale
Cr_f0 = 0.168
Cr_frq0 = 1e-10
Cr_gam0 = 0.047 * eV_um_scale
Cr_sig0 = Cr_f0 * Cr_plasma_frq**2 / Cr_frq0**2
Cr_f1 = 0.151
Cr_frq1 = 0.121 * eV_um_scale  # 10.247 μm
Cr_gam1 = 3.175 * eV_um_scale
Cr_sig1 = Cr_f1 * Cr_plasma_frq**2 / Cr_frq1**2
Cr_f2 = 0.150
Cr_frq2 = 0.543 * eV_um_scale  # 2.283 μm
Cr_gam2 = 1.305 * eV_um_scale
Cr_sig2 = Cr_f2 * Cr_plasma_frq**2 / Cr_frq2**2
Cr_f3 = 1.149
Cr_frq3 = 1.970 * eV_um_scale  # 0.629 μm
Cr_gam3 = 2.676 * eV_um_scale
Cr_sig3 = Cr_f3 * Cr_plasma_frq**2 / Cr_frq3**2
Cr_f4 = 0.825
Cr_frq4 = 8.775 * eV_um_scale  # 0.141 μm
Cr_gam4 = 1.335 * eV_um_scale
Cr_sig4 = Cr_f4 * Cr_plasma_frq**2 / Cr_frq4**2

Cr_susc = [
    mp.DrudeSusceptibility(frequency=Cr_frq0, gamma=Cr_gam0, sigma=Cr_sig0),
    mp.LorentzianSusceptibility(frequency=Cr_frq1, gamma=Cr_gam1, sigma=Cr_sig1),
    mp.LorentzianSusceptibility(frequency=Cr_frq2, gamma=Cr_gam2, sigma=Cr_sig2),
    mp.LorentzianSusceptibility(frequency=Cr_frq3, gamma=Cr_gam3, sigma=Cr_sig3),
    mp.LorentzianSusceptibility(frequency=Cr_frq4, gamma=Cr_gam4, sigma=Cr_sig4),
]

Cr = mp.Medium(epsilon=1.0, E_susceptibilities=Cr_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# nickel (Ni)

Ni_plasma_frq = 15.92 * eV_um_scale
Ni_f0 = 0.096
Ni_frq0 = 1e-10
Ni_gam0 = 0.048 * eV_um_scale
Ni_sig0 = Ni_f0 * Ni_plasma_frq**2 / Ni_frq0**2
Ni_f1 = 0.100
Ni_frq1 = 0.174 * eV_um_scale  # 7.126 μm
Ni_gam1 = 4.511 * eV_um_scale
Ni_sig1 = Ni_f1 * Ni_plasma_frq**2 / Ni_frq1**2
Ni_f2 = 0.135
Ni_frq2 = 0.582 * eV_um_scale  # 2.130 μm
Ni_gam2 = 1.334 * eV_um_scale
Ni_sig2 = Ni_f2 * Ni_plasma_frq**2 / Ni_frq2**2
Ni_f3 = 0.106
Ni_frq3 = 1.597 * eV_um_scale  # 0.776 μm
Ni_gam3 = 2.178 * eV_um_scale
Ni_sig3 = Ni_f3 * Ni_plasma_frq**2 / Ni_frq3**2
Ni_f4 = 0.729
Ni_frq4 = 6.089 * eV_um_scale  # 0.204 μm
Ni_gam4 = 6.292 * eV_um_scale
Ni_sig4 = Ni_f4 * Ni_plasma_frq**2 / Ni_frq4**2

Ni_susc = [
    mp.DrudeSusceptibility(frequency=Ni_frq0, gamma=Ni_gam0, sigma=Ni_sig0),
    mp.LorentzianSusceptibility(frequency=Ni_frq1, gamma=Ni_gam1, sigma=Ni_sig1),
    mp.LorentzianSusceptibility(frequency=Ni_frq2, gamma=Ni_gam2, sigma=Ni_sig2),
    mp.LorentzianSusceptibility(frequency=Ni_frq3, gamma=Ni_gam3, sigma=Ni_sig3),
    mp.LorentzianSusceptibility(frequency=Ni_frq4, gamma=Ni_gam4, sigma=Ni_sig4),
]

Ni = mp.Medium(epsilon=1.0, E_susceptibilities=Ni_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# palladium (Pd)

Pd_plasma_frq = 9.72 * eV_um_scale
Pd_f0 = 0.330
Pd_frq0 = 1e-10
Pd_gam0 = 0.008 * eV_um_scale
Pd_sig0 = Pd_f0 * Pd_plasma_frq**2 / Pd_frq0**2
Pd_f1 = 0.649
Pd_frq1 = 0.336 * eV_um_scale  # 3.690 μm
Pd_gam1 = 2.950 * eV_um_scale
Pd_sig1 = Pd_f1 * Pd_plasma_frq**2 / Pd_frq1**2
Pd_f2 = 0.121
Pd_frq2 = 0.501 * eV_um_scale  # 2.475 μm
Pd_gam2 = 0.555 * eV_um_scale
Pd_sig2 = Pd_f2 * Pd_plasma_frq**2 / Pd_frq2**2
Pd_f3 = 0.638
Pd_frq3 = 1.659 * eV_um_scale  # 0.747 μm
Pd_gam3 = 4.621 * eV_um_scale
Pd_sig3 = Pd_f3 * Pd_plasma_frq**2 / Pd_frq3**2
Pd_f4 = 0.453
Pd_frq4 = 5.715 * eV_um_scale  # 0.217 μm
Pd_gam4 = 3.236 * eV_um_scale
Pd_sig4 = Pd_f4 * Pd_plasma_frq**2 / Pd_frq4**2

Pd_susc = [
    mp.DrudeSusceptibility(frequency=Pd_frq0, gamma=Pd_gam0, sigma=Pd_sig0),
    mp.LorentzianSusceptibility(frequency=Pd_frq1, gamma=Pd_gam1, sigma=Pd_sig1),
    mp.LorentzianSusceptibility(frequency=Pd_frq2, gamma=Pd_gam2, sigma=Pd_sig2),
    mp.LorentzianSusceptibility(frequency=Pd_frq3, gamma=Pd_gam3, sigma=Pd_sig3),
    mp.LorentzianSusceptibility(frequency=Pd_frq4, gamma=Pd_gam4, sigma=Pd_sig4),
]

Pd = mp.Medium(epsilon=1.0, E_susceptibilities=Pd_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# platinum (Pt)

Pt_plasma_frq = 9.59 * eV_um_scale
Pt_f0 = 0.333
Pt_frq0 = 1e-10
Pt_gam0 = 0.080 * eV_um_scale
Pt_sig0 = Pt_f0 * Pt_plasma_frq**2 / Pt_frq0**2
Pt_f1 = 0.191
Pt_frq1 = 0.780 * eV_um_scale  # 1.590 μm
Pt_gam1 = 0.517 * eV_um_scale
Pt_sig1 = Pt_f1 * Pt_plasma_frq**2 / Pt_frq1**2
Pt_f2 = 0.659
Pt_frq2 = 1.314 * eV_um_scale  # 0.944 μm
Pt_gam2 = 1.838 * eV_um_scale
Pt_sig2 = Pt_f2 * Pt_plasma_frq**2 / Pt_frq2**2
Pt_f3 = 0.547
Pt_frq3 = 3.141 * eV_um_scale  # 0.395 μm
Pt_gam3 = 3.668 * eV_um_scale
Pt_sig3 = Pt_f3 * Pt_plasma_frq**2 / Pt_frq3**2
Pt_f4 = 3.576
Pt_frq4 = 9.249 * eV_um_scale  # 0.134 μm
Pt_gam4 = 8.517 * eV_um_scale
Pt_sig4 = Pt_f4 * Pt_plasma_frq**2 / Pt_frq4**2

Pt_susc = [
    mp.DrudeSusceptibility(frequency=Pt_frq0, gamma=Pt_gam0, sigma=Pt_sig0),
    mp.LorentzianSusceptibility(frequency=Pt_frq1, gamma=Pt_gam1, sigma=Pt_sig1),
    mp.LorentzianSusceptibility(frequency=Pt_frq2, gamma=Pt_gam2, sigma=Pt_sig2),
    mp.LorentzianSusceptibility(frequency=Pt_frq3, gamma=Pt_gam3, sigma=Pt_sig3),
    mp.LorentzianSusceptibility(frequency=Pt_frq4, gamma=Pt_gam4, sigma=Pt_sig4),
]

Pt = mp.Medium(epsilon=1.0, E_susceptibilities=Pt_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# titanium (Ti)

Ti_plasma_frq = 7.29 * eV_um_scale
Ti_f0 = 0.148
Ti_frq0 = 1e-10
Ti_gam0 = 0.082 * eV_um_scale
Ti_sig0 = Ti_f0 * Ti_plasma_frq**2 / Ti_frq0**2
Ti_f1 = 0.899
Ti_frq1 = 0.777 * eV_um_scale  # 1.596 μm
Ti_gam1 = 2.276 * eV_um_scale
Ti_sig1 = Ti_f1 * Ti_plasma_frq**2 / Ti_frq1**2
Ti_f2 = 0.393
Ti_frq2 = 1.545 * eV_um_scale  # 0.802 μm
Ti_gam2 = 2.518 * eV_um_scale
Ti_sig2 = Ti_f2 * Ti_plasma_frq**2 / Ti_frq2**2
Ti_f3 = 0.187
Ti_frq3 = 2.509 * eV_um_scale  # 0.494 μm
Ti_gam3 = 1.663 * eV_um_scale
Ti_sig3 = Ti_f3 * Ti_plasma_frq**2 / Ti_frq3**2
Ti_f4 = 0.001
Ti_frq4 = 19.43 * eV_um_scale  # 0.064 μm
Ti_gam4 = 1.762 * eV_um_scale
Ti_sig4 = Ti_f4 * Ti_plasma_frq**2 / Ti_frq4**2

Ti_susc = [
    mp.DrudeSusceptibility(frequency=Ti_frq0, gamma=Ti_gam0, sigma=Ti_sig0),
    mp.LorentzianSusceptibility(frequency=Ti_frq1, gamma=Ti_gam1, sigma=Ti_sig1),
    mp.LorentzianSusceptibility(frequency=Ti_frq2, gamma=Ti_gam2, sigma=Ti_sig2),
    mp.LorentzianSusceptibility(frequency=Ti_frq3, gamma=Ti_gam3, sigma=Ti_sig3),
    mp.LorentzianSusceptibility(frequency=Ti_frq4, gamma=Ti_gam4, sigma=Ti_sig4),
]

Ti = mp.Medium(epsilon=1.0, E_susceptibilities=Ti_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# tungsten (W)

W_plasma_frq = 13.22 * eV_um_scale
W_f0 = 0.206
W_frq0 = 1e-10
W_gam0 = 0.064 * eV_um_scale
W_sig0 = W_f0 * W_plasma_frq**2 / W_frq0**2
W_f1 = 0.054
W_frq1 = 1.004 * eV_um_scale  # 1.235 μm
W_gam1 = 0.530 * eV_um_scale
W_sig1 = W_f1 * W_plasma_frq**2 / W_frq1**2
W_f2 = 0.166
W_frq2 = 1.917 * eV_um_scale  # 0.647 μm
W_gam2 = 1.281 * eV_um_scale
W_sig2 = W_f2 * W_plasma_frq**2 / W_frq2**2
W_f3 = 0.706
W_frq3 = 3.580 * eV_um_scale  # 0.346 μm
W_gam3 = 3.332 * eV_um_scale
W_sig3 = W_f3 * W_plasma_frq**2 / W_frq3**2
W_f4 = 2.590
W_frq4 = 7.498 * eV_um_scale  # 0.165 μm
W_gam4 = 5.836 * eV_um_scale
W_sig4 = W_f4 * W_plasma_frq**2 / W_frq4**2

W_susc = [
    mp.DrudeSusceptibility(frequency=W_frq0, gamma=W_gam0, sigma=W_sig0),
    mp.LorentzianSusceptibility(frequency=W_frq1, gamma=W_gam1, sigma=W_sig1),
    mp.LorentzianSusceptibility(frequency=W_frq2, gamma=W_gam2, sigma=W_sig2),
    mp.LorentzianSusceptibility(frequency=W_frq3, gamma=W_gam3, sigma=W_sig3),
    mp.LorentzianSusceptibility(frequency=W_frq4, gamma=W_gam4, sigma=W_sig4),
]

W = mp.Medium(epsilon=1.0, E_susceptibilities=W_susc, valid_freq_range=metal_range)

# ------------------------------------------------------------------
# metals from D. Barchiesi and T. Grosges, J. Nanophotonics, Vol. 8, 083097 (2014)
# including Errata from J. Nanophotonics, Vol. 8, 089996 (2014)
# wavelength range: 0.4 - 0.8 μm

metal_visible_range = mp.FreqRange(min=um_scale / 0.8, max=um_scale / 0.4)

# gold (Au)
# fit to P.B. Johnson and R.W. Christy, Physical Review B, Vol. 6, pp. 4370-9 (1972)

Au_JC_visible_frq0 = 1 / (0.139779231751333 * um_scale)
Au_JC_visible_gam0 = 1 / (26.1269913352870 * um_scale)
Au_JC_visible_sig0 = 1

Au_JC_visible_frq1 = 1 / (0.404064525036786 * um_scale)
Au_JC_visible_gam1 = 1 / (1.12834046202759 * um_scale)
Au_JC_visible_sig1 = 2.07118534879440

Au_JC_visible_susc = [
    mp.DrudeSusceptibility(
        frequency=Au_JC_visible_frq0, gamma=Au_JC_visible_gam0, sigma=Au_JC_visible_sig0
    ),
    mp.LorentzianSusceptibility(
        frequency=Au_JC_visible_frq1, gamma=Au_JC_visible_gam1, sigma=Au_JC_visible_sig1
    ),
]

Au_JC_visible = mp.Medium(
    epsilon=6.1599,
    E_susceptibilities=Au_JC_visible_susc,
    valid_freq_range=metal_visible_range,
)

# ------------------------------------------------------------------
# gold (Au)
# fit to E.D. Palik, Handbook of Optical Constants, Academic Press (1985)

Au_visible_frq0 = 1 / (0.0473629248511456 * um_scale)
Au_visible_gam0 = 1 / (0.255476199605166 * um_scale)
Au_visible_sig0 = 1

Au_visible_frq1 = 1 / (0.800619321082804 * um_scale)
Au_visible_gam1 = 1 / (0.381870287531951 * um_scale)
Au_visible_sig1 = -169.060953137985

Au_visible_susc = [
    mp.DrudeSusceptibility(
        frequency=Au_visible_frq0, gamma=Au_visible_gam0, sigma=Au_visible_sig0
    ),
    mp.LorentzianSusceptibility(
        frequency=Au_visible_frq1, gamma=Au_visible_gam1, sigma=Au_visible_sig1
    ),
]

Au_visible = mp.Medium(
    epsilon=0.6888,
    E_susceptibilities=Au_visible_susc,
    valid_freq_range=metal_visible_range,
)

# ------------------------------------------------------------------
## WARNING: unstable; field divergence may occur

# silver (Au)
# fit to E.D. Palik, Handbook of Optical Constants, Academic Press (1985)

Ag_visible_frq0 = 1 / (0.142050162130618 * um_scale)
Ag_visible_gam0 = 1 / (18.0357292925015 * um_scale)
Ag_visible_sig0 = 1

Ag_visible_frq1 = 1 / (0.115692151792108 * um_scale)
Ag_visible_gam1 = 1 / (0.257794324096575 * um_scale)
Ag_visible_sig1 = 3.74465275944019

Ag_visible_susc = [
    mp.DrudeSusceptibility(
        frequency=Ag_visible_frq0, gamma=Ag_visible_gam0, sigma=Ag_visible_sig0
    ),
    mp.LorentzianSusceptibility(
        frequency=Ag_visible_frq1, gamma=Ag_visible_gam1, sigma=Ag_visible_sig1
    ),
]

Ag_visible = mp.Medium(
    epsilon=0.0067526,
    E_susceptibilities=Ag_visible_susc,
    valid_freq_range=metal_visible_range,
)

# ------------------------------------------------------------------
## WARNING: unstable; field divergence may occur

# aluminum (Al)
# fit to E.D. Palik, Handbook of Optical Constants, Academic Press (1985)

Al_visible_frq0 = 1 / (0.0625841659042985 * um_scale)
Al_visible_gam0 = 1 / (0.606007002962666 * um_scale)
Al_visible_sig0 = 1

Al_visible_frq1 = 1 / (0.528191199577075 * um_scale)
Al_visible_gam1 = 1 / (0.291862527666814 * um_scale)
Al_visible_sig1 = -44.4456675577921

Al_visible_susc = [
    mp.DrudeSusceptibility(
        frequency=Al_visible_frq0, gamma=Al_visible_gam0, sigma=Al_visible_sig0
    ),
    mp.LorentzianSusceptibility(
        frequency=Al_visible_frq1, gamma=Al_visible_gam1, sigma=Al_visible_sig1
    ),
]

Al_visible = mp.Medium(
    epsilon=0.13313,
    E_susceptibilities=Al_visible_susc,
    valid_freq_range=metal_visible_range,
)

# ------------------------------------------------------------------
# chroimium (Cr)
# fit to E.D. Palik, Handbook of Optical Constants, Academic Press (1985)

Cr_visible_frq0 = 1 / (0.118410119507342 * um_scale)
Cr_visible_gam0 = 1 / (0.628596264869804 * um_scale)
Cr_visible_sig0 = 1

Cr_visible_frq1 = 1 / (0.565709598452496 * um_scale)
Cr_visible_gam1 = 1 / (0.731117670900812 * um_scale)
Cr_visible_sig1 = 13.2912419951294

Cr_visible_susc = [
    mp.DrudeSusceptibility(
        frequency=Cr_visible_frq0, gamma=Cr_visible_gam0, sigma=Cr_visible_sig0
    ),
    mp.LorentzianSusceptibility(
        frequency=Cr_visible_frq1, gamma=Cr_visible_gam1, sigma=Cr_visible_sig1
    ),
]

Cr_visible = mp.Medium(
    epsilon=2.7767,
    E_susceptibilities=Cr_visible_susc,
    valid_freq_range=metal_visible_range,
)

# ------------------------------------------------------------------
# titanium (Ti)
# fit to E.D. Palik, Handbook of Optical Constants, Academic Press (1985)

Ti_visible_frq0 = 1 / (0.2213799986964903 * um_scale)
Ti_visible_gam0 = 1 / (12.815176733218491 * um_scale)
Ti_visible_sig0 = 1

Ti_visible_frq1 = 1 / (0.6425774603632576 * um_scale)
Ti_visible_gam1 = 1 / (0.1738808794709548 * um_scale)
Ti_visible_sig1 = 74.4496

Ti_visible_susc = [
    mp.DrudeSusceptibility(
        frequency=Ti_visible_frq0, gamma=Ti_visible_gam0, sigma=Ti_visible_sig0
    ),
    mp.LorentzianSusceptibility(
        frequency=Ti_visible_frq1, gamma=Ti_visible_gam1, sigma=Ti_visible_sig1
    ),
]

Ti_visible = mp.Medium(
    epsilon=2.17069,
    E_susceptibilities=Ti_visible_susc,
    valid_freq_range=metal_visible_range,
)

# ------------------------------------------------------------------
# aluminum (Al) from Horiba Technical Note 09: Drude Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Drude_Dispersion_Model.pdf
# wavelength range: 0.19 - 0.83 μm

Al_drude_range = mp.FreqRange(min=um_scale / 0.83, max=um_scale / 0.19)

Al_drude_frq = 1 / (0.0789607648707171 * um_scale)
Al_drude_gam = 1 / (1.78138208333333 * um_scale)
Al_drude_sig = 1

Al_drude_susc = [
    mp.DrudeSusceptibility(
        frequency=Al_drude_frq, gamma=Al_drude_gam, sigma=Al_drude_sig
    )
]

Al_drude = mp.Medium(
    epsilon=1.0, E_susceptibilities=Al_drude_susc, valid_freq_range=Al_drude_range
)

# ------------------------------------------------------------------
# cobalt (Co) from Horiba Technical Note 09: Drude Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Drude_Dispersion_Model.pdf
# wavelength range: 0.26 - 1.65 μm

Co_range = mp.FreqRange(min=um_scale / 1.65, max=um_scale / 0.26)

Co_frq = 1 / (0.0789607648707171 * um_scale)
Co_gam = 1 / (0.213802712536644 * um_scale)
Co_sig = 1

Co_susc = [mp.DrudeSusceptibility(frequency=Co_frq, gamma=Co_gam, sigma=Co_sig)]

Co = mp.Medium(epsilon=3.694, E_susceptibilities=Co_susc, valid_freq_range=Co_range)

# ------------------------------------------------------------------
## WARNING: unstable; field divergence may occur

# molybdenum (Mo) from Horiba Technical Note 09: Drude Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Drude_Dispersion_Model.pdf
# wavelength range: 0.25 - 0.83 μm

Mo_range = mp.FreqRange(min=um_scale / 0.83, max=um_scale / 0.25)

Mo_frq = 1 / (0.0620790071099539 * um_scale)
Mo_gam = 1 / (0.148359690080172 * um_scale)
Mo_sig = 1

Mo_susc = [mp.DrudeSusceptibility(frequency=Mo_frq, gamma=Mo_gam, sigma=Mo_sig)]

Mo = mp.Medium(epsilon=-1.366, E_susceptibilities=Mo_susc, valid_freq_range=Mo_range)

# ------------------------------------------------------------------
# nickel chrome (NiCr) from Horiba Technical Note 09: Drude Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Drude_Dispersion_Model.pdf
# wavelength range: 0.25 - 0.83 μm

NiCr_range = mp.FreqRange(min=um_scale / 0.83, max=um_scale / 0.25)

NiCr_frq = 1 / (0.0868845080588648 * um_scale)
NiCr_gam = 1 / (0.308418390547264 * um_scale)
NiCr_sig = 1

NiCr_susc = [mp.DrudeSusceptibility(frequency=NiCr_frq, gamma=NiCr_gam, sigma=NiCr_sig)]

NiCr = mp.Medium(epsilon=1.0, E_susceptibilities=NiCr_susc, valid_freq_range=NiCr_range)

# ------------------------------------------------------------------
# nickel iron (NiFe) from Horiba Technical Note 09: Drude Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Drude_Dispersion_Model.pdf
# wavelength range: 0.25 - 0.83 μm

NiFe_range = mp.FreqRange(min=um_scale / 0.83, max=um_scale / 0.25)

NiFe_frq = 1 / (0.0838297450980392 * um_scale)
NiFe_gam = 1 / (0.259381156903766 * um_scale)
NiFe_sig = 1

NiFe_susc = [mp.DrudeSusceptibility(frequency=NiFe_frq, gamma=NiFe_gam, sigma=NiFe_sig)]

NiFe = mp.Medium(epsilon=1.0, E_susceptibilities=NiFe_susc, valid_freq_range=NiFe_range)

# ------------------------------------------------------------------
# titanium (Ti) from Horiba Technical Note 09: Drude Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Drude_Dispersion_Model.pdf
# wavelength range: 0.21 - 1.24 μm

Ti_drude_range = mp.FreqRange(min=um_scale / 1.24, max=um_scale / 0.21)

Ti_drude_frq = 1 / (0.113746966055046 * um_scale)
Ti_drude_gam = 1 / (0.490056098814229 * um_scale)
Ti_drude_sig = 1

Ti_drude_susc = [
    mp.DrudeSusceptibility(
        frequency=Ti_drude_frq, gamma=Ti_drude_gam, sigma=Ti_drude_sig
    )
]

Ti_drude = mp.Medium(
    epsilon=1.0, E_susceptibilities=Ti_drude_susc, valid_freq_range=Ti_drude_range
)

# ------------------------------------------------------------------
# silicon nitride (SiN), non-stoichiometric, from Horiba Technical Note 08: Lorentz Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Lorentz_Dispersion_Model.pdf
# wavelength range: 0.21 - 2.07 μm

SiN_range = mp.FreqRange(min=um_scale / 2.07, max=um_scale / 0.21)

SiN_frq1 = 1 / (0.190891752117013 * um_scale)
SiN_gam1 = 1 / (3.11518072864322 * um_scale)
SiN_sig1 = 1.2650

SiN_susc = [
    mp.LorentzianSusceptibility(frequency=SiN_frq1, gamma=SiN_gam1, sigma=SiN_sig1)
]

SiN = mp.Medium(epsilon=2.320, E_susceptibilities=SiN_susc, valid_freq_range=SiN_range)

# ------------------------------------------------------------------
# silicon nitride (Si3N4), stoichiometric, from Horiba Technical Note 08: Lorentz Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Lorentz_Dispersion_Model.pdf
# wavelength range: 0.23 - 0.83 μm

Si3N4_range = mp.FreqRange(min=um_scale / 0.83, max=um_scale / 0.23)

Si3N4_frq1 = 1 / (0.389153148148148 * um_scale)
Si3N4_gam1 = 1 / (0.693811936205932 * um_scale)
Si3N4_sig1 = 4.377

Si3N4_susc = [
    mp.LorentzianSusceptibility(
        frequency=Si3N4_frq1, gamma=Si3N4_gam1, sigma=Si3N4_sig1
    )
]

Si3N4 = mp.Medium(
    epsilon=1.0, E_susceptibilities=Si3N4_susc, valid_freq_range=Si3N4_range
)

# ------------------------------------------------------------------
# silicon dioxide (SiO2) from Horiba Technical Note 08: Lorentz Dispersion Model
# ref: http://www.horiba.com/fileadmin/uploads/Scientific/Downloads/OpticalSchool_CN/TN/ellipsometer/Lorentz_Dispersion_Model.pdf
# wavelength range: 0.25 - 1.77 μm

SiO2_range = mp.FreqRange(min=um_scale / 1.77, max=um_scale / 0.25)

SiO2_frq1 = 1 / (0.103320160833333 * um_scale)
SiO2_gam1 = 1 / (12.3984193000000 * um_scale)
SiO2_sig1 = 1.12

SiO2_susc = [
    mp.LorentzianSusceptibility(frequency=SiO2_frq1, gamma=SiO2_gam1, sigma=SiO2_sig1)
]

SiO2 = mp.Medium(epsilon=1.0, E_susceptibilities=SiO2_susc, valid_freq_range=SiO2_range)

# ------------------------------------------------------------------
# indium phosphide (InP) from Handbook of Optics, 2nd edition, Vol. 2, McGraw-Hill (1994)
# ref: https://refractiveindex.info/?shelf=main&book=InP&page=Pettit
# wavelength range: 0.95 - 10 μm

InP_range = mp.FreqRange(min=um_scale / 10, max=um_scale / 0.95)

InP_frq1 = 1 / (0.6263 * um_scale)
InP_gam1 = 0
InP_sig1 = 2.316
InP_frq2 = 1 / (32.935 * um_scale)
InP_gam2 = 0
InP_sig2 = 2.765

InP_susc = [
    mp.LorentzianSusceptibility(frequency=InP_frq1, gamma=InP_gam1, sigma=InP_sig1),
    mp.LorentzianSusceptibility(frequency=InP_frq2, gamma=InP_gam2, sigma=InP_sig2),
]

InP = mp.Medium(epsilon=7.255, E_susceptibilities=InP_susc, valid_freq_range=InP_range)

# ------------------------------------------------------------------
# germanium (Ge) from N. P. Barnes and M. S. Piltch, J. Optical Society America, Vol. 69, pp. 178-180 (1979)
# ref: https://refractiveindex.info/?shelf=main&book=Ge&page=Icenogle
# wavelength range: 2.5 - 12 μm

Ge_range = mp.FreqRange(min=um_scale / 12, max=um_scale / 2.5)

Ge_frq1 = 1 / (0.6641159 * um_scale)
Ge_gam1 = 0
Ge_sig1 = 6.7288
Ge_frq2 = 1 / (62.210127 * um_scale)
Ge_gam2 = 0
Ge_sig2 = 0.21307

Ge_susc = [
    mp.LorentzianSusceptibility(frequency=Ge_frq1, gamma=Ge_gam1, sigma=Ge_sig1),
    mp.LorentzianSusceptibility(frequency=Ge_frq2, gamma=Ge_gam2, sigma=Ge_sig2),
]

Ge = mp.Medium(epsilon=9.28156, E_susceptibilities=Ge_susc, valid_freq_range=Ge_range)

# ------------------------------------------------------------------
# silicon (Si) from C. D. Salzberg and J. J. Villa, , J. Optical Society America, Vol. 47, pp. 244-246 (1957)
# ref: https://refractiveindex.info/?shelf=main&book=Si&page=Salzberg
# wavelength range: 1.36 - 11 μm

Si_range = mp.FreqRange(min=um_scale / 11, max=um_scale / 1.36)

Si_frq1 = 1 / (0.301516485 * um_scale)
Si_gam1 = 0
Si_sig1 = 10.6684293
Si_frq2 = 1 / (1.13475115 * um_scale)
Si_gam2 = 0
Si_sig2 = 0.0030434748
Si_frq3 = 1 / (1104 * um_scale)
Si_gam3 = 0
Si_sig3 = 1.54133408

Si_susc = [
    mp.LorentzianSusceptibility(frequency=Si_frq1, gamma=Si_gam1, sigma=Si_sig1),
    mp.LorentzianSusceptibility(frequency=Si_frq2, gamma=Si_gam2, sigma=Si_sig2),
    mp.LorentzianSusceptibility(frequency=Si_frq3, gamma=Si_gam3, sigma=Si_sig3),
]

Si = mp.Medium(epsilon=1.0, E_susceptibilities=Si_susc, valid_freq_range=Si_range)

# ------------------------------------------------------------------
# poly(methyl methacrylate) (PMMA) from N. Sultanova et al., Acta Physica Polonica A, Vol. 116, pp. 585-7 (2009)
# ref: https://refractiveindex.info/?shelf=organic&book=poly%28methyl_methacrylate%29&page=Sultanova
# wavelength range: 0.437 - 1.052 μm

PMMA_range = mp.FreqRange(min=um_scale / 1.052, max=um_scale / 0.437)

PMMA_frq1 = 1 / (0.106362587407415 * um_scale)
PMMA_gam1 = 0
PMMA_sig1 = 1.1819

PMMA_susc = [
    mp.LorentzianSusceptibility(frequency=PMMA_frq1, gamma=PMMA_gam1, sigma=PMMA_sig1)
]

PMMA = mp.Medium(epsilon=1.0, E_susceptibilities=PMMA_susc, valid_freq_range=PMMA_range)

# ------------------------------------------------------------------
# polycarbonate (PC) from N. Sultanova et al., Acta Physica Polonica A, Vol. 116, pp. 585-7 (2009)
# ref: https://refractiveindex.info/?shelf=organic&book=polycarbonate&page=Sultanova
# wavelength range: 0.437 - 1.052 μm

PC_range = mp.FreqRange(min=um_scale / 1.052, max=um_scale / 0.437)

PC_frq1 = 1 / (0.145958898324152 * um_scale)
PC_gam1 = 0
PC_sig1 = 1.4182

PC_susc = [mp.LorentzianSusceptibility(frequency=PC_frq1, gamma=PC_gam1, sigma=PC_sig1)]

PC = mp.Medium(epsilon=1.0, E_susceptibilities=PC_susc, valid_freq_range=PC_range)

# ------------------------------------------------------------------
# polystyrene (PS) from N. Sultanova et al., Acta Physica Polonica A, Vol. 116, pp. 585-7 (2009)
# ref: https://refractiveindex.info/?shelf=organic&book=polystyren&page=Sultanova
# wavelength range: 0.437 - 1.052 μm

PS_range = mp.FreqRange(min=um_scale / 1.052, max=um_scale / 0.437)

PS_frq1 = 1 / (0.142182980697410 * um_scale)
PS_gam1 = 0
PS_sig1 = 1.4435

PS_susc = [mp.LorentzianSusceptibility(frequency=PS_frq1, gamma=PS_gam1, sigma=PS_sig1)]

PS = mp.Medium(epsilon=1.0, E_susceptibilities=PS_susc, valid_freq_range=PS_range)

# ------------------------------------------------------------------
# cellulose (CLS) from N. Sultanova et al., Acta Physica Polonica A, Vol. 116, pp. 585-7 (2009)
# ref: https://refractiveindex.info/?shelf=organic&book=cellulose&page=Sultanova
# wavelength range: 0.437 - 1.052 μm

CLS_range = mp.FreqRange(min=um_scale / 1.052, max=um_scale / 0.437)

CLS_frq1 = 1 / (0.105294824184287 * um_scale)
CLS_gam1 = 0
CLS_sig1 = 1.124

CLS_susc = [
    mp.LorentzianSusceptibility(frequency=CLS_frq1, gamma=CLS_gam1, sigma=CLS_sig1)
]

CLS = mp.Medium(epsilon=1.0, E_susceptibilities=CLS_susc, valid_freq_range=CLS_range)

# ------------------------------------------------------------------
# barium borate (BaB2O4), beta phase, from G. Tamosauskas et al., Optical Materials Express, Vol. 8, pp. 1410-18 (2018)
# ref: https://refractiveindex.info/?shelf=main&book=BaB2O4&page=Tamosauskas-o
# ref: https://refractiveindex.info/?shelf=main&book=BaB2O4&page=Tamosauskas-e
# wavelength range: 0.188 - 5.2 μm

## NOTE: ordinary (o) axes in X and Y, extraordinary (e) axis in Z

BaB2O4_range = mp.FreqRange(min=um_scale / 5.2, max=um_scale / 0.188)

BaB2O4_frq1 = 1 / (0.06265780079128216 * um_scale)
BaB2O4_gam1 = 0
BaB2O4_sig1 = 0.90291
BaB2O4_frq2 = 1 / (0.13706202975295528 * um_scale)
BaB2O4_gam2 = 0
BaB2O4_sig2 = 0.83155
BaB2O4_frq3 = 1 / (7.746612162745725 * um_scale)
BaB2O4_gam3 = 0
BaB2O4_sig3 = 0.76536

BaB2O4_susc_o = [
    mp.LorentzianSusceptibility(
        frequency=BaB2O4_frq1,
        gamma=BaB2O4_gam1,
        sigma_diag=BaB2O4_sig1 * mp.Vector3(1, 1, 0),
    ),
    mp.LorentzianSusceptibility(
        frequency=BaB2O4_frq2,
        gamma=BaB2O4_gam2,
        sigma_diag=BaB2O4_sig2 * mp.Vector3(1, 1, 0),
    ),
    mp.LorentzianSusceptibility(
        frequency=BaB2O4_frq3,
        gamma=BaB2O4_gam3,
        sigma_diag=BaB2O4_sig3 * mp.Vector3(1, 1, 0),
    ),
]

BaB2O4_frq1 = 1 / (0.0845103543951864 * um_scale)
BaB2O4_gam1 = 0
BaB2O4_sig1 = 1.151075
BaB2O4_frq2 = 1 / (0.15029970059850417 * um_scale)
BaB2O4_gam2 = 0
BaB2O4_sig2 = 0.21803
BaB2O4_frq3 = 1 / (16.217274740226856 * um_scale)
BaB2O4_gam3 = 0
BaB2O4_sig3 = 0.656

BaB2O4_susc_e = [
    mp.LorentzianSusceptibility(
        frequency=BaB2O4_frq1,
        gamma=BaB2O4_gam1,
        sigma_diag=BaB2O4_sig1 * mp.Vector3(0, 0, 1),
    ),
    mp.LorentzianSusceptibility(
        frequency=BaB2O4_frq2,
        gamma=BaB2O4_gam2,
        sigma_diag=BaB2O4_sig2 * mp.Vector3(0, 0, 1),
    ),
    mp.LorentzianSusceptibility(
        frequency=BaB2O4_frq3,
        gamma=BaB2O4_gam3,
        sigma_diag=BaB2O4_sig3 * mp.Vector3(0, 0, 1),
    ),
]

BaB2O4 = mp.Medium(
    epsilon=1.0,
    E_susceptibilities=BaB2O4_susc_o + BaB2O4_susc_e,
    valid_freq_range=BaB2O4_range,
)

# ------------------------------------------------------------------
# lithium niobate (LiNbO3) from D.E. Zelmon et al., J. Optical Society of America B, Vol. 14, pp. 3319-22 (1997)
# ref: https://refractiveindex.info/?shelf=main&book=LiNbO3&page=Zelmon-o
# ref: https://refractiveindex.info/?shelf=main&book=LiNbO3&page=Zelmon-e
# wavelength range: 0.4 - 5.0 μm

## NOTE: ordinary (o) axes in X and Y, extraordinary (e) axis in Z

LiNbO3_range = mp.FreqRange(min=um_scale / 5.0, max=um_scale / 0.4)

LiNbO3_frq1 = 1 / (0.13281566172707193 * um_scale)
LiNbO3_gam1 = 0
LiNbO3_sig1 = 2.6734
LiNbO3_frq2 = 1 / (0.24318717071424636 * um_scale)
LiNbO3_gam2 = 0
LiNbO3_sig2 = 1.2290
LiNbO3_frq3 = 1 / (21.78531615561271 * um_scale)
LiNbO3_gam3 = 0
LiNbO3_sig3 = 12.614

LiNbO3_susc_o = [
    mp.LorentzianSusceptibility(
        frequency=LiNbO3_frq1,
        gamma=LiNbO3_gam1,
        sigma_diag=LiNbO3_sig1 * mp.Vector3(1, 1, 0),
    ),
    mp.LorentzianSusceptibility(
        frequency=LiNbO3_frq2,
        gamma=LiNbO3_gam2,
        sigma_diag=LiNbO3_sig2 * mp.Vector3(1, 1, 0),
    ),
    mp.LorentzianSusceptibility(
        frequency=LiNbO3_frq3,
        gamma=LiNbO3_gam3,
        sigma_diag=LiNbO3_sig3 * mp.Vector3(1, 1, 0),
    ),
]

LiNbO3_frq1 = 1 / (0.14307340773183533 * um_scale)
LiNbO3_gam1 = 0
LiNbO3_sig1 = 2.9804
LiNbO3_frq2 = 1 / (0.2580697580112788 * um_scale)
LiNbO3_gam2 = 0
LiNbO3_sig2 = 0.5981
LiNbO3_frq3 = 1 / (20.39803912144498 * um_scale)
LiNbO3_gam3 = 0
LiNbO3_sig3 = 8.9543

LiNbO3_susc_e = [
    mp.LorentzianSusceptibility(
        frequency=LiNbO3_frq1,
        gamma=LiNbO3_gam1,
        sigma_diag=LiNbO3_sig1 * mp.Vector3(0, 0, 1),
    ),
    mp.LorentzianSusceptibility(
        frequency=LiNbO3_frq2,
        gamma=LiNbO3_gam2,
        sigma_diag=LiNbO3_sig2 * mp.Vector3(0, 0, 1),
    ),
    mp.LorentzianSusceptibility(
        frequency=LiNbO3_frq3,
        gamma=LiNbO3_gam3,
        sigma_diag=LiNbO3_sig3 * mp.Vector3(0, 0, 1),
    ),
]

LiNbO3 = mp.Medium(
    epsilon=1.0,
    E_susceptibilities=LiNbO3_susc_o + LiNbO3_susc_e,
    valid_freq_range=LiNbO3_range,
)

# ------------------------------------------------------------------
# calcium tungstate (CaWO4) from W.L. Bond, J. Applied Physics, Vol. 36, pp. 1674-77 (1965)
# ref: https://refractiveindex.info/?shelf=main&book=CaWO4&page=Bond-o
# ref: https://refractiveindex.info/?shelf=main&book=CaWO4&page=Bond-e
# wavelength range: 0.45 - 4.0 μm

## NOTE: ordinary (o) axes in X and Y, extraordinary (e) axis in Z

CaWO4_range = mp.FreqRange(min=um_scale / 4.0, max=um_scale / 0.45)

CaWO4_frq1 = 1 / (0.1347 * um_scale)
CaWO4_gam1 = 0
CaWO4_sig1 = 2.5493
CaWO4_frq2 = 1 / (10.815 * um_scale)
CaWO4_gam2 = 0
CaWO4_sig2 = 0.9200

CaWO4_susc_o = [
    mp.LorentzianSusceptibility(
        frequency=CaWO4_frq1,
        gamma=CaWO4_gam1,
        sigma_diag=CaWO4_sig1 * mp.Vector3(1, 1, 0),
    ),
    mp.LorentzianSusceptibility(
        frequency=CaWO4_frq2,
        gamma=CaWO4_gam2,
        sigma_diag=CaWO4_sig2 * mp.Vector3(1, 1, 0),
    ),
]

CaWO4_frq1 = 1 / (0.1379 * um_scale)
CaWO4_gam1 = 0
CaWO4_sig1 = 2.6041
CaWO4_frq2 = 1 / (21.371 * um_scale)
CaWO4_gam2 = 0
CaWO4_sig2 = 4.1237

CaWO4_susc_e = [
    mp.LorentzianSusceptibility(
        frequency=CaWO4_frq1,
        gamma=CaWO4_gam1,
        sigma_diag=CaWO4_sig1 * mp.Vector3(0, 0, 1),
    ),
    mp.LorentzianSusceptibility(
        frequency=CaWO4_frq2,
        gamma=CaWO4_gam2,
        sigma_diag=CaWO4_sig2 * mp.Vector3(0, 0, 1),
    ),
]

CaWO4 = mp.Medium(
    epsilon=1.0,
    E_susceptibilities=CaWO4_susc_o + CaWO4_susc_e,
    valid_freq_range=CaWO4_range,
)

# ------------------------------------------------------------------
# calcium carbonate (CaCO3) from G. Ghosh, Optics Communication, Vol. 163, pp. 95-102 (1999)
# ref: https://refractiveindex.info/?shelf=main&book=CaCO3&page=Ghosh-o
# ref: https://refractiveindex.info/?shelf=main&book=CaCO3&page=Ghosh-e
# wavelength range: 0.204 - 2.172 μm

## NOTE: ordinary (o) axes in X and Y, extraordinary (e) axis in Z

CaCO3_range = mp.FreqRange(min=um_scale / 2.172, max=um_scale / 0.204)

CaCO3_frq1 = 1 / (0.13940057496294625 * um_scale)
CaCO3_gam1 = 0
CaCO3_sig1 = 0.96464345
CaCO3_frq2 = 1 / (10.954451150103322 * um_scale)
CaCO3_gam2 = 0
CaCO3_sig2 = 1.82831454

CaCO3_susc_o = [
    mp.LorentzianSusceptibility(
        frequency=CaCO3_frq1,
        gamma=CaCO3_gam1,
        sigma_diag=CaCO3_sig1 * mp.Vector3(1, 1, 0),
    ),
    mp.LorentzianSusceptibility(
        frequency=CaCO3_frq2,
        gamma=CaCO3_gam2,
        sigma_diag=CaCO3_sig2 * mp.Vector3(1, 1, 0),
    ),
]

CaCO3_frq1 = 1 / (0.1032906302623815 * um_scale)
CaCO3_gam1 = 0
CaCO3_sig1 = 0.82427830
CaCO3_frq2 = 1 / (10.954451150103322 * um_scale)
CaCO3_gam2 = 0
CaCO3_sig2 = 0.14429128

CaCO3_susc_e = [
    mp.LorentzianSusceptibility(
        frequency=CaCO3_frq1,
        gamma=CaCO3_gam1,
        sigma_diag=CaCO3_sig1 * mp.Vector3(0, 0, 1),
    ),
    mp.LorentzianSusceptibility(
        frequency=CaCO3_frq2,
        gamma=CaCO3_gam2,
        sigma_diag=CaCO3_sig2 * mp.Vector3(0, 0, 1),
    ),
]

CaCO3 = mp.Medium(
    epsilon_diag=mp.Vector3(1.73358749, 1.73358749, 1.35859695),
    E_susceptibilities=CaCO3_susc_o + CaCO3_susc_e,
    valid_freq_range=CaCO3_range,
)

# ------------------------------------------------------------------
# silicon dioxide (SiO2) from G. Ghosh, Optics Communication, Vol. 163, pp. 95-102 (1999)
# ref: https://refractiveindex.info/?shelf=main&book=SiO2&page=Ghosh-o
# ref: https://refractiveindex.info/?shelf=main&book=SiO2&page=Ghosh-e
# wavelength range: 0.198 - 2.0531 μm

## NOTE: ordinary (o) axes in X and Y, extraordinary (e) axis in Z

SiO2_range = mp.FreqRange(min=um_scale / 2.0531, max=um_scale / 0.198)

SiO2_frq1 = 1 / (0.10029257051247614 * um_scale)
SiO2_gam1 = 0
SiO2_sig1 = 1.07044083
SiO2_frq2 = 1 / (10 * um_scale)
SiO2_gam2 = 0
SiO2_sig2 = 1.10202242

SiO2_susc_o = [
    mp.LorentzianSusceptibility(
        frequency=SiO2_frq1, gamma=SiO2_gam1, sigma_diag=SiO2_sig1 * mp.Vector3(1, 1, 0)
    ),
    mp.LorentzianSusceptibility(
        frequency=SiO2_frq2, gamma=SiO2_gam2, sigma_diag=SiO2_sig2 * mp.Vector3(1, 1, 0)
    ),
]

SiO2_frq1 = 1 / (0.10104546699382412 * um_scale)
SiO2_gam1 = 0
SiO2_sig1 = 1.09509924
SiO2_frq2 = 1 / (10 * um_scale)
SiO2_gam2 = 0
SiO2_sig2 = 1.15662475

SiO2_susc_e = [
    mp.LorentzianSusceptibility(
        frequency=SiO2_frq1, gamma=SiO2_gam1, sigma_diag=SiO2_sig1 * mp.Vector3(0, 0, 1)
    ),
    mp.LorentzianSusceptibility(
        frequency=SiO2_frq2, gamma=SiO2_gam2, sigma_diag=SiO2_sig2 * mp.Vector3(0, 0, 1)
    ),
]

SiO2_aniso = mp.Medium(
    epsilon_diag=mp.Vector3(1.28604141, 1.28604141, 1.28851804),
    E_susceptibilities=SiO2_susc_o + SiO2_susc_e,
    valid_freq_range=SiO2_range,
)

# ------------------------------------------------------------------
# gallium nitride (GaN), alpha phase (wurtzite), from A.S. Barker Jr. and M. Ilegems, Physical Review B, Vol. 7, pp. 743-50 (1973)
# ref: https://refractiveindex.info/?shelf=main&book=GaN&page=Barker-o
# ref: https://refractiveindex.info/?shelf=main&book=GaN&page=Barker-e
# wavelength range: 0.35 - 10 μm

## NOTE: ordinary (o) axes in X and Y, extraordinary (e) axis in Z

GaN_range = mp.FreqRange(min=um_scale / 10.0, max=um_scale / 0.35)

GaN_frq1 = 1 / (0.256 * um_scale)
GaN_gam1 = 0
GaN_sig1 = 1.75
GaN_frq2 = 1 / (17.86 * um_scale)
GaN_gam2 = 0
GaN_sig2 = 4.1

GaN_susc_o = [
    mp.LorentzianSusceptibility(
        frequency=GaN_frq1, gamma=GaN_gam1, sigma_diag=GaN_sig1 * mp.Vector3(1, 1, 0)
    ),
    mp.LorentzianSusceptibility(
        frequency=GaN_frq2, gamma=GaN_gam2, sigma_diag=GaN_sig2 * mp.Vector3(1, 1, 0)
    ),
]

GaN_frq1 = 1 / (18.76 * um_scale)
GaN_gam1 = 0
GaN_sig1 = 5.08

GaN_susc_e = [
    mp.LorentzianSusceptibility(
        frequency=GaN_frq1, gamma=GaN_gam1, sigma_diag=GaN_sig1 * mp.Vector3(0, 0, 1)
    )
]

GaN = mp.Medium(
    epsilon_diag=mp.Vector3(3.6, 3.6, 5.35),
    E_susceptibilities=GaN_susc_o + GaN_susc_e,
    valid_freq_range=GaN_range,
)

# ------------------------------------------------------------------
# aluminum nitride (AlN) from J. Pastrnak and L. Roskovcova, Physica Status Solidi, Vol. 14, K5-8 (1966)
# ref: https://refractiveindex.info/?shelf=main&book=AlN&page=Pastrnak-o
# ref: https://refractiveindex.info/?shelf=main&book=AlN&page=Pastrnak-e
# wavelength range: 0.22 - 5 μm

## NOTE: ordinary (o) axes in X and Y, extraordinary (e) axis in Z

AlN_range = mp.FreqRange(min=um_scale / 5.0, max=um_scale / 0.22)

AlN_frq1 = 1 / (0.1715 * um_scale)
AlN_gam1 = 0
AlN_sig1 = 1.3786
AlN_frq2 = 1 / (15.03 * um_scale)
AlN_gam2 = 0
AlN_sig2 = 3.861

AlN_susc_o = [
    mp.LorentzianSusceptibility(
        frequency=AlN_frq1, gamma=AlN_gam1, sigma_diag=AlN_sig1 * mp.Vector3(1, 1, 0)
    ),
    mp.LorentzianSusceptibility(
        frequency=AlN_frq2, gamma=AlN_gam2, sigma_diag=AlN_sig2 * mp.Vector3(1, 1, 0)
    ),
]

AlN_frq1 = 1 / (0.1746 * um_scale)
AlN_gam1 = 0
AlN_sig1 = 1.6173
AlN_frq2 = 1 / (15.03 * um_scale)
AlN_gam2 = 0
AlN_sig2 = 4.139

AlN_susc_e = [
    mp.LorentzianSusceptibility(
        frequency=AlN_frq1, gamma=AlN_gam1, sigma_diag=AlN_sig1 * mp.Vector3(0, 0, 1)
    ),
    mp.LorentzianSusceptibility(
        frequency=AlN_frq2, gamma=AlN_gam2, sigma_diag=AlN_sig2 * mp.Vector3(0, 0, 1)
    ),
]

AlN_aniso = mp.Medium(
    epsilon_diag=mp.Vector3(3.1399, 3.1399, 3.0729),
    E_susceptibilities=AlN_susc_o + AlN_susc_e,
    valid_freq_range=AlN_range,
)

# ------------------------------------------------------------------
# alumina/sapphire (Al2O3) from I.H. Malitson and M.J. Dodge, J. Optical Society of America, Vol. 62, pp. 1405 (1972)
# ref: https://refractiveindex.info/?shelf=main&book=Al2O3&page=Malitson-o
# ref: https://refractiveindex.info/?shelf=main&book=Al2O3&page=Malitson-e
# wavelength range: 0.2 - 5 μm

## NOTE: ordinary (o) axes in X and Y, extraordinary (e) axis in Z

Al2O3_range = mp.FreqRange(min=um_scale / 5.0, max=um_scale / 0.2)

Al2O3_frq1 = 1 / (0.0726631 * um_scale)
Al2O3_gam1 = 0
Al2O3_sig1 = 1.4313493
Al2O3_frq2 = 1 / (0.1193242 * um_scale)
Al2O3_gam2 = 0
Al2O3_sig2 = 0.65054713
Al2O3_frq3 = 1 / (18.02825 * um_scale)
Al2O3_gam3 = 0
Al2O3_sig3 = 5.3414021

Al2O3_susc_o = [
    mp.LorentzianSusceptibility(
        frequency=Al2O3_frq1,
        gamma=Al2O3_gam1,
        sigma_diag=Al2O3_sig1 * mp.Vector3(1, 1, 0),
    ),
    mp.LorentzianSusceptibility(
        frequency=Al2O3_frq2,
        gamma=Al2O3_gam2,
        sigma_diag=Al2O3_sig2 * mp.Vector3(1, 1, 0),
    ),
    mp.LorentzianSusceptibility(
        frequency=Al2O3_frq3,
        gamma=Al2O3_gam3,
        sigma_diag=Al2O3_sig3 * mp.Vector3(1, 1, 0),
    ),
]

Al2O3_frq1 = 1 / (0.0740288 * um_scale)
Al2O3_gam1 = 0
Al2O3_sig1 = 1.5039759
Al2O3_frq2 = 1 / (0.1216529 * um_scale)
Al2O3_gam2 = 0
Al2O3_sig2 = 0.55069141
Al2O3_frq3 = 1 / (20.072248 * um_scale)
Al2O3_gam3 = 0
Al2O3_sig3 = 6.5927379

Al2O3_susc_e = [
    mp.LorentzianSusceptibility(
        frequency=Al2O3_frq1,
        gamma=Al2O3_gam1,
        sigma_diag=Al2O3_sig1 * mp.Vector3(0, 0, 1),
    ),
    mp.LorentzianSusceptibility(
        frequency=Al2O3_frq2,
        gamma=Al2O3_gam2,
        sigma_diag=Al2O3_sig2 * mp.Vector3(0, 0, 1),
    ),
    mp.LorentzianSusceptibility(
        frequency=Al2O3_frq3,
        gamma=Al2O3_gam3,
        sigma_diag=Al2O3_sig3 * mp.Vector3(0, 0, 1),
    ),
]

Al2O3_aniso = mp.Medium(
    epsilon=1,
    E_susceptibilities=Al2O3_susc_o + Al2O3_susc_e,
    valid_freq_range=Al2O3_range,
)

# ------------------------------------------------------------------
# yttrium oxide (Y2O3) from Y. Nigara, Japanese J. of Applied Physics, Vol. 7, pp. 404-8 (1968)
# ref: https://refractiveindex.info/?shelf=main&book=Y2O3&page=Nigara
# wavelength range: 0.25 - 9.6 μm

Y2O3_range = mp.FreqRange(min=um_scale / 9.6, max=um_scale / 0.25)

Y2O3_frq1 = 1 / (0.1387 * um_scale)
Y2O3_gam1 = 0
Y2O3_sig1 = 2.578
Y2O3_frq2 = 1 / (22.936 * um_scale)
Y2O3_gam2 = 0
Y2O3_sig2 = 3.935

Y2O3_susc = [
    mp.LorentzianSusceptibility(frequency=Y2O3_frq1, gamma=Y2O3_gam1, sigma=Y2O3_sig1),
    mp.LorentzianSusceptibility(frequency=Y2O3_frq2, gamma=Y2O3_gam2, sigma=Y2O3_sig2),
]

Y2O3 = mp.Medium(epsilon=1.0, E_susceptibilities=Y2O3_susc, valid_freq_range=Y2O3_range)

# ------------------------------------------------------------------
# undoped yttrium aluminum garnet (YAG) from D.E. Zelmon et al., Applied Optics, Vol. 37, 4933-5 (1998)
# ref: https://refractiveindex.info/?shelf=main&book=Y3Al5O12&page=Zelmon
# wavelength range: 0.4 - 5.0 μm

YAG_range = mp.FreqRange(min=um_scale / 5.0, max=um_scale / 0.4)

YAG_frq1 = 1 / (0.1088577052853862 * um_scale)
YAG_gam1 = 0
YAG_sig1 = 2.28200
YAG_frq2 = 1 / (16.814695953242804 * um_scale)
YAG_gam2 = 0
YAG_sig2 = 3.27644

YAG_susc = [
    mp.LorentzianSusceptibility(frequency=YAG_frq1, gamma=YAG_gam1, sigma=YAG_sig1),
    mp.LorentzianSusceptibility(frequency=YAG_frq2, gamma=YAG_gam2, sigma=YAG_sig2),
]

YAG = mp.Medium(epsilon=1.0, E_susceptibilities=YAG_susc, valid_freq_range=YAG_range)

# ------------------------------------------------------------------
# cadmium telluride (CdTe) from D.T.F. Marple, J. Applied Physics, Vol. 35, pp. 539-42 (1964)
# ref: https://refractiveindex.info/?shelf=main&book=CdTe&page=Marple
# wavelength range: 0.86 - 2.5 μm

CdTe_range = mp.FreqRange(min=um_scale / 2.5, max=um_scale / 0.86)

CdTe_frq1 = 1 / (0.6049793384901669 * um_scale)
CdTe_gam1 = 0
CdTe_sig1 = 1.53

CdTe_susc = [
    mp.LorentzianSusceptibility(frequency=CdTe_frq1, gamma=CdTe_gam1, sigma=CdTe_sig1)
]

CdTe = mp.Medium(
    epsilon=5.68, E_susceptibilities=CdTe_susc, valid_freq_range=CdTe_range
)
